研究文章

光电复合型氢气传感器研究进展:从机理到智能化应用

摘要

氢能作为未来能源体系的重要组成部分,其安全利用高度依赖于高性能的泄漏检测技术。传统的电学型传感器受限于工作温度高、存在引燃风险,而纯光学传感器系统复杂、成本高昂。光电复合型氢气传感器利用局域表面等离激元共振热电子注入、光催化降低反应能垒以及光控肖特基结势垒调制等机制,成功实现了超灵敏检测和快速响应。本文重点阐述了光电协同增强的物理机制,系统总结了基于硅基异质结、金属氧化物及二维材料的代表性器件性能,展望了该领域未来的发展方向。

关键词

氢气传感器;光电复合;局域等离激元;热电子;肖特基结

参考

张翔宇, 等. 氢气传感技术研究进展 [J]. 华东理工大学学报 (自然科学版), 2025, 51(6): 731-747.

Jin, C., et al. Detection of micro-scale Li dendrite via H2 gas capture for early safety warning. Joule, 2020.4(8), 1714-1729.

Song, Y.,et al.. Early Warning of Lithium-Ion Battery Thermal Runaway Based on Gas Sensors. eTransportation, 2025, 26, 100502.

Wang, Z.et al. Gas Sensing Technology for the Detection and Early Warning of Battery Thermal Runaway: A Review.ENERGY & FUELS, 2022,36, 6038–6057.

晏萌, 等. 氢气传感器的研究及应用进展 [J]. 西华大学学报 (自然科学版), 2025, 44(1): 75-91.

Korotcenkov, G. Metal Oxides for Solid-State Gas Sensors: What Determines Our Choice? Materials Science and Engineering: B, 2007,139, 1–23.

Wang, J. et al. Light-Activated Room-Temperature Gas Sensors Based on Metal Oxide Nanostructures: A Review on Recent Advances. Ceramics International, 2021, 47, 7353–7368.

Liao, Z., et al. A Survey of Methods for Monitoring and Detecting Thermal Runaway of Lithium-Ion Batteries.Journal of Power Sources, 2019, 436, 226879.

Song, Y., et al.. Early Warning of Lithium-Ion Battery Thermal Runaway Based on Gas Sensors. eTransportation, 2025,26, 100502.

Brongersma, M. L.,et al. Plasmon-Induced Hot Carrier Science and Technology. Nature Nanotechnology, 2015, 10, 25–34.

Mukherjee, S., et al.. Hot Electrons Do the Impossible: Plasmon-Induced Dissociation of H2 on Au. NANO LETTERS, 2012,13, 240–247.

Sil, D., et al.. Seeing Is Believing: Hot Electron Based Gold Nanoplasmonic Optical Hydrogen Sensor. ACS Nano, 2014, 8, 7755–7762.

Darmadi, I., et al. High-Performance Nanostructured Palladium-Based Hydrogen Sensors—Current Limitations and Strategies for Their Mitigation. ACS Sensors, 2020,5, 3306–3327.

Fan, S.W.,et al. UV-Activated Room-Temperature Gas Sensing Mechanism of Polycrystalline ZnO.APPLIED PHYSICS LETTERS, 2009,95.

Wang, J.,et al. Light-Activated Room-Temperature Gas Sensors Based on Metal Oxide Nanostructures: A Review on Recent Advances. Ceramics International, 2021,47, 7353–7368.

Prades, J. D., et al. Equivalence between Thermal and Room Temperature UV Light-Modulated Responses of Gas Sensors Based on Individual SnO2 Nanowires.Sensors and Actuators B: Chemical, 2009,140, 337–341.

Mao F., et al. A CMOS-compatible and cost-effective room temperature sensitive hydrogen sensor [J]. Sensors and Actuators B: Chemical, 2024, 418: 136322.

Xu X., et al. High-Performance Hydrogen Sensors for ppb-Level Detection at Room Temperature Using Pd Nanoparticle-Coated Si Nanoforest [J]. ACS Sensors, 2025, 10: 5781–5790.

Song Z., et al. Nano-Schottky-junction-engineered Pd/SnO2 nanotube array for ultrasensitive hydrogen sensing at room temperature [J]. Analytical Methods, 2024, 16: 5954–5958.

Kim J-Y., et al. Machine learning-guided analysis of room-temperature H2 gas sensing using Au- and Pd-decorated ZnO sensors [J]. Journal of Alloys and Compounds, 2025, 1040: 183606.

LI, J., et al. Photodetectors Based on Two-Dimensional Materials and Their van Der Waals Heterostructures.Acta Physico-Chimica Sinica, 2019,35, 1058–1077.

Herran M., et al.Plasmonic bimetallic two-dimensional supercrystals for H2 generation. Nat Catal, 2023,6, 1205–1214.

Theodoridis, A., et al. A Catalytic-Plasmonic Pt Nanoparticle Sensor for Hydrogen Detection in High-Humidity Environments. ACS Sensors, 2025, 10, 8983–8994.

Refbacks

  • 当前没有refback。
版权所有(c)2026 华龙 高, 荣煌 刘, 凡 李, 娇 池
Creative Commons License
此作品已接受知识共享署名-非商业性使用 4.0国际许可协议的许可。